Random First Order Transition Theory for Glassy Dynamics in a Single Condensed Polymer

نویسندگان

چکیده

The number of compact structures a single condensed polymer (SCP), with similar free energies, grows exponentially the degree polymerization. In analogy structural glasses (SGs), we expect that at low temperatures chain relaxation should occur by activated transitions between metastable states. By evolving states SCP, linearly coupled to reference state, show that, below dynamical transition temperature (${T}_{d}$), SCP is trapped in state leading slow dynamics. At lower temperature, ${T}_{K}\ensuremath{\ne}0$, configurational entropy vanishes, resulting thermodynamic random first order ideal glass transition. time obeys Vogel-Fulcher-Tamman law, diverging $T={T}_{0}\ensuremath{\approx}{T}_{K}$. These findings, accord well theory, establishing and SG exhibit universal characteristics.

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ژورنال

عنوان ژورنال: Physical Review Letters

سال: 2021

ISSN: ['1079-7114', '0031-9007', '1092-0145']

DOI: https://doi.org/10.1103/physrevlett.126.137801